To obtain the serial number easily on an environment with the removable media attached, the following command can be run in a Powershell window:
From an Endpoint detection standpoint, an API call is made on both Mac and Windows operating systems rather than a direct query of Device Manager. The DLP reports lists this value from its received incident information.
Please note that Mac machines did not support the use of serial numbers for identification until Forcepoint One build 19.10.
Note The following article describes a similar procedure for Mac environments:
Determining serial numbers within Endpoint Devices for macOS DLP policies